The solution‐based reaction in dry THF and under nitrogen atmosphere at 50 °C with either zinc flakes or granular zinc (no additive used) resulted in low yields of 7 and 4 %, respectively (Scheme 4 B), whereas under ball‐milling conditions without any solvent, inert gas, or additive (Table 2), the reaction proceeded smoothly in 2 h and all forms of zinc explored were effective for this
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WhatsAppGet PriceGet A QuoteRampura Agucha is the second largest zinc mine in the world with a production of 3.9 million MT in FY 2020. It stands apart as a world class ore body with zinc-lead reserve grade averaging 14.2%. Total Reserve are 39 million MT and mineral resources are 45.8 million MT as on March 31, 2020. The mine has a production capacity of 4.5 million MT per annum.
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WhatsAppGet PriceGet A QuoteA ball-milling-enabled zinc-mediated Barbier-type allylation reaction is reported. Notably, running the reaction in this manner renders it effective irrespective of the initial morphology of the zinc metal. The process is operationally simple, does not require inert atmospheres or dry solvents, and is reported over a range of aldehyde and ketone substrates; a gram-scale process is demonstrated.
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WhatsAppGet PriceGet A QuoteThe major use of the conventional ball milling is to fracture the particles and to reduce the size, which is different from the newly established high energy ball milling (HEBM) method. In this new method a magnet is placed close to the cell to apply a strong magnetic pulling force on the magnetic milling balls, and therefore the impact energy is much higher than the conventional ball milling
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