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A ball mill also known as pebble mill or tumbling mill is a milling machine that consists of a hallow cylinder containing balls; mounted on a metallic frame such that it can be rotated along its longitudinal axis. The balls which could be of different diameter occupy 30 – 50 % of the mill volume and its size depends on the feed and mill size.
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Mixtures of these compounds and Clp were mixed with a defined amount of inert SiO 2 and stressed at a frequency of 30 Hz in ZrO 2 jars and balls using a mixer ball mill for t = 1–15 min. Milling times of 15 minutes were sufficient for conversion of 30–40% of Clp (determined by 1 H NMR), depending on the oxidant used.
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